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Influence of pressure and density on the rheological properties of rockfills

Erich BAUER, Zhongzhi FU, Sihong LIU

《结构与土木工程前沿（英文）》 2012年第6卷第1期页码 25-34 doi: 10.1007/s11709-012-0143-0

摘要： Long-term deformations of rockfill dams can be related to the type of dam, the pre-compaction achieved during the construction of the dam, the history of loading events, the rheological properties of the rockfill material used, the seepage behavior caused by defects of the sealing, the interactions of the dam building with the foundation, and the hydrothermal phenomena of the stressed rockfill material. The present paper investigates the rheological properties of coarse grained rockfill materials using a hypoplastic constitutive model. Particular attention is paid to wetting deformation under different deviatoric loading states and pre-compactions. To quantify the state of weathering a so-called “solid hardness” is used in the sense of a continuum description. It is shown that an appropriate modeling of wetting deformations requires a unified description of the interaction at least between the state of weathering, the stress state, the density and the rate of deformation. The results obtained from the numerical simulations are compared with available experimental data for a rockfill material used in Xiaolangdi earth dam.

关键词： rockfills solid hardness wetting deformation hypoplasticity creep

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Hypoplastic constitutive modeling of wetting deformation of weathered rockfill materials

Erich BAUER, Zhongzhi FU, Sihong LIU,

《结构与土木工程前沿（英文）》 2010年第4卷第1期页码 78-91 doi: 10.1007/s11709-010-0011-8

摘要： The wetting deformation of weathered rockfill materials has been attracting growing attention from both engineers and scientists. The importance of realistic predictions of wetting deformations for high earth and rockfill dams is a strong motivation to establish a suitable constitutive model. Recently, the hypoplastic constitutive model by Gudehus and Bauer was extended by introducing solid hardness depending on the state of weathering. The extended model takes into account the influence of the current density, the effective stress state, the rate of deformation, and the time dependent process of degradation of the solid hardness. In the present paper, the performance of this model is evaluated by comparing numerical simulations with experiments obtained from a water sensitive rockfill material. In particular, triaxial compression paths and creep deformation under deviatoric stress states are considered. Finally, the constitutive model proposed is used to study the influence of a degradation of the solid hardness on the long term behavior of a hypothetical fill dam.

关键词： rockfill dams weathered granular materials hypoplasticity solid hardness creep stress relaxation

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Research on overlaying welding rod of high hardness maraging steel

PAN Yong-ming, CHEN Shao-wei

《机械工程前沿（英文）》 2006年第1卷第4期页码 465-467 doi: 10.1007/s11465-006-0060-9

摘要： The development of new maraging steel overlaying welding rod, which contains Co, Mo, W and V alloy, solved the problems of poor homogeneity of hardness and mechanical process, prolonged the service life of wear-resistant components and increased the productive efficiency of repairing, greatly benefiting the national economy.

关键词： development productive efficiency national homogeneity mechanical

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Development of soft kernel durum wheat

Craig F. MORRIS

《农业科学与工程前沿（英文）》 2019年第6卷第3期页码 273-278 doi: 10.15302/J-FASE-2019259

摘要：

Kernel texture (grain hardness) is a fundamental and determining factor related to wheat ( spp.) milling, baking and flour utilization. There are three kernel texture classes in wheat: soft and hard hexaploid ( ), and very hard durum ( subsp. ). The genetic basis for these three classes lies with the Puroindoline genes. Phenotypically, the easiest means of quantifying kernel texture is with the Single Kernel Characterization System (SKCS), although other means are valid and can provide fundamental material properties. Typical SKCS values for soft wheat would be around 25 and for durum wheat≥80. Soft kernel durum wheat was created via homeologous recombination using the mutation, which facilitated the transfer of ca. 28 Mbp of 5DS that replaced ca. 21 Mbp of 5BS. The 5DS translocation contained a complete and intact locus and both puroindoline genes. Expression of the puroindoline genes in durum grain resulted in kernel texture and flour milling characteristics nearly identical to that of soft wheat, with high yields of break and straight-grade flours, which had small particle size and low starch damage. Dough water absorption was markedly reduced compared to durum flour and semolina. Dough was essentially unchanged and reflected the inherent gluten properties of the durum background. Pasta quality was essentially equal-to-or-better than pasta made from semolina. Agronomically, soft durum germplasm showed good potential with moderate grain yield and resistance to a number of fungal pathogens and insects. Future breeding efforts will no doubt further improve the quality and competitiveness of soft durum cultivars.

关键词： soft durum wheat grain hardness puroindolines milling baking pasta noodles

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Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

《能源前沿（英文）》 doi: 10.1007/s11708-023-0901-9

摘要： Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance degradation of SOCs. Coating on the interconnector surface is an important approach to inhibit the oxidation and Cr migration of the interconnector. Herein, (La_0.75Sr_0.25)_0.95MnO_3–δ (LSM) and Mn_1.5Co_1.5O₄ (MCO) are used to fabricate the coatings of interconnector. Two advanced thermal spray technology, atmospheric plasma spraying (APS) and low-pressure plasma spray (LPPS), are adopted for the coating preparation. The electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition performance of the coatings are tested and evaluated. The result indicates that MCO can generate more uniform and denser coatings than LSM. In addition, MCO coatings prepared by LPPS shows the best electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition. The initial area specific resistance (ASR) is 0.0027 Ω·cm² at 800 °C. After 4 cooling cycle tests, the ASR increases to 0.0032 Ω·cm² but lower than other samples. Meanwhile, the relative intense of Cr at the interface of SUS430 with MCO coatings fabricated by LPPS is lower than that of MCO fabricated by APS after 4 rising and cooling cycle operations, showing more favorable Cr diffusion inhibition performance.

关键词： interconnector coating plasma spray electrochemical performance Cr diffusion inhibition solid oxide cells (SOCs)

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Minimal residual disease in solid tumors: an overview

《医学前沿（英文）》 2023年第17卷第4期页码 649-674 doi: 10.1007/s11684-023-1018-6

摘要： Minimal residual disease (MRD) is termed as the small numbers of remnant tumor cells in a subset of patients with tumors. Liquid biopsy is increasingly used for the detection of MRD, illustrating the potential of MRD detection to provide more accurate management for cancer patients. As new techniques and algorithms have enhanced the performance of MRD detection, the approach is becoming more widely and routinely used to predict the prognosis and monitor the relapse of cancer patients. In fact, MRD detection has been shown to achieve better performance than imaging methods. On this basis, rigorous investigation of MRD detection as an integral method for guiding clinical treatment has made important advances. This review summarizes the development of MRD biomarkers, techniques, and strategies for the detection of cancer, and emphasizes the application of MRD detection in solid tumors, particularly for the guidance of clinical treatment.

关键词： MRD solid tumor CTC ctDNA

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High-solid anaerobic digestion of sewage sludge: achievements and perspectives

《环境科学与工程前沿（英文）》 2021年第15卷第4期 doi: 10.1007/s11783-020-1364-4

摘要：

• High-solid anaerobic digestion (HS-AD) of sewage sludge (SS) is overviewed.

关键词： High-solid effect Anaerobic fermentation Methane production Biodegradability Sludge treatment

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Review of SO42-/MxOy solid superacid catalysts

Yanni WU, Shijun LIAO

《化学科学与工程前沿（英文）》 2009年第3卷第3期页码 330-343 doi: 10.1007/s11705-009-0208-3

摘要： Some metal oxides modified with sulfate ions form highly acidic or superacidic catalysts. solid superacid catalysts, play a vital role in more and more fields such as organic synthesis, fine chemicals, pharmaceuticals, and means for strengthening environmental safeguards. This review highlights the recent development of solid superacid catalysts based on , including synthesis method, characterization of acid sites and acid strength, and applications.

关键词： solid superacid catalyst synthesis method characterization applications

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Repercussions of COVID-19 pandemic on solid waste generation and management strategies

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1407-5

摘要：

• Implication of COVID-19 on medical waste and MSW generation is studied.

关键词： COVID-19 Medical waste Personal protective equipment Municipal solid waste Waste management

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Municipal solid waste management in Dalian: practices and challenges

Xinbei WANG, Yong GENG

《环境科学与工程前沿（英文）》 2012年第6卷第4期页码 540-548 doi: 10.1007/s11783-011-0361-z

摘要： The fast growing of urban areas in developing countries has brought serious problems on municipal solid waste (MSW) management. It will be rational to adopt an integrated approach to deal with such a challenge so that the overall eco-efficiency of MSW management could be improved. To better examine how attributes of integrated MSW management are being interpreted and put into practice, and to explore what changes should be made to improve the application of integrated MSW management, we employ a case study method so that lessons learned could be used to inform initiatives in other cities and the potential solution may offer feasible strategies. The case study city is Dalian, a typical seaport city with fast growing rate in economy. The outcomes of this case study show us that fragmented management structure, ineffective and inefficient enforcement of relevant regulations, backward technologies, limited financial resources and lack of public participation are main barriers for the implementation of integrated MSW management. Consequently, in order to overcome these barriers, we propose an integrated management framework on MSW management, aiming to maximize the overall eco-efficiency of MSW management.

关键词： municipal solid waste (MSW) management 3R principles challenges eco-efficiency effective and efficient enforcement

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Evaluation of groundwater quality in the Xinjiang Plain Area

Jinlong ZHOU, Xinguang DONG, Yiping WANG, Guomin LI, Xiaojing GUO,

《环境科学与工程前沿（英文）》 2010年第4卷第2期页码 183-186 doi: 10.1007/s11783-010-0021-8

摘要： Groundwater is the main source of drinking water for the urban and rural residents in the plain area of the Xinjiang Uygur Autonomous Region, China. The quality of groundwater has a direct relationship with human health. Thus, 386 groundwater samples collected from April to August in 2003 were analyzed. The samples were collected in basic evaluation units which are determined on the basis of watersheds. Total dissolved solids, total hardness, pH value, NH–N, CHOH, Chemiluminescence detection of permanganate index (COD) and intestinal germ group were evaluated according to the guidelines of Groundwater Quality Standard (GB/T14848-93). The quality of the groundwater in each evaluation unit was classified by using the One Veto Method (a unified approach stipulated by the Ministry of Water Resources). The results indicate that the groundwater in the mainstream area of the Tarim Basin and the Yerqiang River Sub-basin belongs to Category V; the groundwater in the Wulungu River Sub-basin, the Kaidu-Kongque River Sub-basin, the Kashgar River Sub-basin, the Cherchen River Sub-basin and the Hotan River Sub-basin belongs to Category IV; the groundwater in the Aibi Lake System belongs to Category II, and the groundwater of other evaluation units belongs to Category III. The causes of water quality formation were concisely analyzed. The results can be useful for the evaluation and management of water resources in the Xinjiang Plain Area.

关键词： groundwater quality evaluation one veto method total dissolved solids (TDS) pH total hardness

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Lagrangian simulation of deposition of CO gas-solid sudden expansion flow

HUANG Dongping, DING Guoliang, QUACK Hans

《能源前沿（英文）》 2008年第2卷第2期页码 216-221 doi: 10.1007/s11708-008-0032-3

摘要： Freezing and blockage resulting from the deposition of solid CO formed because of sudden expansion of the downstream pipe during the release of CO through safety valves, will endanger the protected equipment. To overcome this problem, the characteristics of the CO gas-solid sudden expansion flow are studied by using the disperse Lagrangian model. A comparison of the calculated deposition of the solid CO with the experimental results shows that they are in reasonable agreement. The simulation results show that the size of the solid CO formed should not be in the range of 0.04–0.07 mm ( number 3.2–9.8). This can be achieved by using an appropriate flow cross section of the safety valve.

关键词： comparison gas-solid downstream blockage Lagrangian

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Development and prospects of municipal solid waste (MSW) incineration in China

NIE Yongfeng

《环境科学与工程前沿（英文）》 2008年第2卷第1期页码 1-7 doi: 10.1007/s11783-008-0028-6

摘要： With the lack of space for new landfills, municipal solid waste (MSW) incineration is playing an increasingly important role in municipal solid waste management in China. The literatures on certain aspects of incineration plants in China are reviewed in this paper, including the development and status of the application of MSW incineration technologies, the treatment of leachate from stored MSW, air pollution control technologies, and the status of the fly-ash control method. Energy policy and its promotion of MSW-to-energy conversion are also elucidated.

关键词： development management municipal MSW incineration

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Surface molecularly imprinted polymers for solid-phase extraction of (--)-epigallocatechin gallate from

Yunling Gao,Ying Hu,Kejian Yao

《化学科学与工程前沿（英文）》 2015年第9卷第4期页码 467-478 doi: 10.1007/s11705-015-1526-2

摘要： Surface molecularly imprinted polymers (SMIPs) have been synthesized to selectively determine (−)-epigallocatechin gallate in aqueous media. SMIPs were prepared using a surface grafting copolymerization method on a functionalized silica gel modified with -cyclodextrin and vinyl groups. The morphology and composition of the SMIPs were investigated by scanning electron microscopy, Fourier transform-infrared spectroscopy and thermogravimetric analysis. In addition, the molecular binding capacity, recognition properties and selectivity of the SMIPs were evaluated. The imprinted polymers were found to have a highly specific recognition and binding capacity for (−)-epigallocatechin gallate in aqueous media which is the result of the hydrophobic properties of the -cyclodextrin and the hydrogen-bonding interactions of methacrylic acid. The SMIPs were successfully employed as solid-phase extraction adsorbents prior to the HPLC determination of (−)-epigallocatechin gallate in toothpaste. The HPLC analysis had a linear dynamic range of 0.5–50.0 µg?mL with a correlation coefficient of 0.9998 and the recoveries ranged from 89.4% to 97.0% with relative standard deviations less than 4.8%. The limit of detection and limit of quantification were 0.17 and 0.33 µg?mL , respectively. The method provides a promising approach for the preparation of selective materials for the purification and determination of complex samples.

关键词： β-cyclodextrin (−)-epigallocatechin gallate surface molecular imprinting solid-phase extraction

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Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Cyrine Ayed, Wei Huang, Kai A. I. Zhang

《化学科学与工程前沿（英文）》 2020年第14卷第3期页码 397-404 doi: 10.1007/s11705-019-1884-2

摘要： Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.

关键词： photocatalysis covalent triazine framework aqueous medium SBA-15 solid state